Pure metals generally have

(a) high conductivity and low temperature coefficient
(b) high conductivity and large temperature coefficient
(c) low conductivity and zero temperature coefficient
(d) low conductivity and high temperature coefficient

Correct Answer: (b)

Explanation

Pure metals conduct well and show significant resistance change with temperature.

Notes for More Information

Temperature Effect on Conductivity and Resistivity

In Metals

1.    Pure metals have very high electrical conductivity.

2.    This is because metals contain a large number of free electrons.

3.    When temperature increases:

·        The number of free electrons remains almost constant.

·        But the mobility of electrons decreases.

4.    The decrease in mobility is due to increased lattice vibrations of metal atoms.

5.    These vibrations cause more collisions (lattice scattering) between electrons and atoms.

6.    As a result, resistivity increases.

7.    Hence, metals have a positive temperature coefficient of resistivity.


In Semiconductors

8.    In semiconductors, the behavior is different.

9.    When temperature increases:

·        More electrons gain energy.

·        Electrons are excited from the valence band to the conduction band.

10.                    This leads to a large increase in carrier concentration.

11.                    Due to more charge carriers:

·        Conductivity increases

·        Resistivity decreases

12.                    Therefore, semiconductors have a negative temperature coefficient of resistivity.

13.                    In intrinsic semiconductors, the dominant factor is the increase in the number of free electrons.

14.                    Hence, the specific resistance of semiconductors decreases with increasing temperature.


Key Difference Between Metals and Semiconductors

15.                    The difference in temperature behavior arises mainly due to:

·        Metals → carrier concentration remains constant; mobility decreases.

·        Semiconductors → carrier concentration increases rapidly with temperature.

16.                    Thus, the variation of resistance with temperature is fundamentally different for metals and semiconductors.


Important Conclusion (MCQ-Oriented)

17.                    Pure metals generally have:

·        High electrical conductivity

·        Large temperature coefficient of resistance

18.                    This means:

·        They conduct electricity very well.

·        Their resistance increases significantly with temperature.

19.                    Hence, the correct option is (b): high conductivity and large temperature coefficient.


Contrast with Alloys

20.                    Alloys (such as manganin and constantan):

·        Have lower conductivity than pure metals.

·        Possess very small or nearly zero temperature coefficient.

21.                    Because of this, alloys are preferred for:

·        Precision resistors

·        Stable resistance applications, where temperature variation must have minimal effect.


Final Takeaway

22.                    Metals → High conductivity, positive and large temperature coefficient.

23.                    Semiconductors → Conductivity increases with temperature, negative temperature coefficient.

24.                    Alloys → Lower conductivity but excellent resistance stability with temperature




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